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Monsanto

Safety Data Sheet

1. IDENTIFICATION

Preparation

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Roundup® RTU Faster Acting Formula

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Company

Monsanto Roundup Lawn & Garden - Salisbury House, Weyside Park,

Catteshall Lane - Godalming, Surrey GU7 1XE - United Kingdom -

Tel. +44 (0)1483 410210 - Fax +44(0)1483 410220

Emergency telephone

Antwerp, Belgium +32(0)3.5685123 * UK +44(0)1865.407333

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2. COMPOSITION/INFORMATION ON INGREDIENTS

Active ingredient

Isopropylamine salt of Glyphosate = Isopropylamine salt of

N-(phosphonomethyl) glycine

Composition (approximate)

ca 1 % w/w Isopropylamine salt of Glyphosate

CAS No. : 38641-94-0 , EU No. : 254-056-8

(= 0.71 % w/w Glyphosate)

ca 94 % w/w Water

ca 5 % w/w Minor Formulating ingredients

Application

Herbicide

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3. HAZARDS IDENTIFICATION

Human health effects

On the basis of available information, this material is not

expected to produce any significant adverse health effects when

recommended use instructions are followed.

Environmental effects

On the basis of available information, this material is not

expected to produce any significant adverse environmental effects

when recommended use instructions are followed.

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4. FIRST-AID MEASURES

Skin contact

Wash with plenty of water.

Grossly contaminated clothing

Remove contaminated clothing.

Wash before re-use.

Eye contact

Rinse with plenty of potable water/sterile eye wash solution.

Inhalation

Not applicable.

Ingestion

Obtain medical advice.

Medical advice

No symptoms diagnostic of systemic poisoning with this product.

No specific antidote. Treat symptomatically.

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5. FIRE FIGHTING MEASURES

Not applicable; non flammable.

Keep containers cool by spraying with water if exposed to fire.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Follow all recommended handling procedures.

Environmental precautions

Low environmental hazard.

Methods for cleaning up

Small quantities: flush spill area with water.

Large quantities: absorb in earth or sand.

Sweep up into containers for disposal.

Flush spill area with water.

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7. HANDLING AND STORAGE

Handling

Good industrial practice in housekeeping and personal hygiene

should be followed.

Use only in totally sealed systems (Spray cans: Ready to use).

When using do not eat, drink or smoke.

Wash hands thoroughly after handling or contact.

For more information refer to product label.

Storage

Keep out of the reach of children.

Keep away from food, drink and animal feedingstuffs.

Keep only in the original container.

Store above 0°C.

Do not store above 45°C for prolonged time.

Exposure to a maximum of 55°C for as long as two weeks will not

degrade this product.

Minimum shelf life: 2 years.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering measures

Not applicable.

Occupational exposure limit

Not applicable.

Respiratory protection

No special requirement when used as recommended.

Hand protection

No special requirement when used as recommended.

Eye protection

No special requirement when used as recommended.

Skin protection

No special requirement when used as recommended.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: solution, pale milky white

Flash point: not applicable, non flammable

pH: 6.8

Specific gravity: 1.0155 (20 °C)

Water solubility: completely miscible

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10. STABILITY AND REACTIVITY

Conditions to avoid

Heating > 100 °C may generate pressure due to steam formation from

the water present.

Materials to avoid

Warning: Avoid all direct contact of this material with galvanised

or unlined steel (except stainless steel) as it will react to

produce hydrogen, a highly flammable gas that can cause explosions.

Hazardous decomposition products

Phosphorus pentoxide , carbon monoxide (CO), nitrogen

oxides (NOx).

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11. TOXICOLOGICAL INFORMATION

Laboratory data

Similar formulation

Oral LD50 (rat): > 5000 mg/kg

Dermal LD50 (rabbit): > 5000 mg/kg

Overall mean EU eye irritation scores (24 h exposure) (rabbit):

conjunctival redness: 0.5

conjunctival swelling: 0.06

corneal opacity: 0

iris lesions: 0

Overall mean EU skin irritation scores (OECD test)(rabbit, 4 h

exposure):

redness: 0

swelling: 0

Guinea pig Buehler test: 5 % positive incidence.

Inhalation LC50 (rat) (aerosol): > 10 mg/l, the highest

achievable concentration in this study.

Active ingredient

Tests on glyphosate showed that it did not cause any mutagenic,

carcinogenic, teratogenic or adverse reproductive effects.

It is not neurotoxic.

Human data

None.

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12. ECOLOGICAL INFORMATION

Test results

Similar formulation

Aquatic toxicity

LC50, 96 h:

Golden orfe (Leuciscus idus): 491 mg/l.

Rainbow trout (Oncorhynchus mykiss): 322 mg/l.

EC50, 48 h:

Water flea (Daphnia magna): 1634 mg/l.

EbC50, 72 h:

Algae (Selenastrum capricornutum): 15 mg/l.

Active ingredient

Avian toxicity

LD50, Acute, Oral:

Bobwhite quail (Colinus Virginianus): > 3851 mg/kg body weight.

LC50, 8 day dietary (5 day treatment):

Mallard duck (Anas platyrhynchos): > 4640 mg/kg diet.

Bobwhite quail (Colinus Virginianus): > 4640 mg/kg diet.

Wildlife toxicity

LD50, 48 h, Topical:

Honey bee (Apis mellifera): > 100 microg/bee.

LD50, 48 h, Oral:

Honey bee (Apis mellifera): > 100 microg/bee.

Bioaccumulation

Tests in a variety of mammalian/avian/aquatic species: no

bioaccumulation.

Dissipation

Glyphosate in surface water: 50 % dissipation: +/- 4 days

90 % dissipation: < 20 days

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13. DISPOSAL CONSIDERATIONS

Product

Small quantities: present no environmental problem.

Large quantities: send to special chemical waste disposal

facility or burn only in special, controlled high temperature

incinerator.

Containers

Empty packages completely.

Give them to public waste disposal services.

Do not re-use containers.

Do not contaminate waterways, ponds or ditches.

All local and national regulations should be followed.

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14. TRANSPORT INFORMATION

Not regulated for transport.

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15. REGULATORY INFORMATION

EU label (in accordance with the Pesticides Directive 78/631)

Not classified as dangerous.

Other regulation

All local and national regulations should be followed.

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16. OTHER INFORMATION

This Safety Data Sheet has been prepared following the EU

Directive 93/112.

The information given here is not necessarily exhaustive but is

representative of relevant, reliable data.

All tests were conducted following OECD guidelines for Good

Laboratory Practices (GLP).

® Registered Trademark of Monsanto

Please consult Monsanto if further information is needed.

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The information in this data sheet is to the best of our knowledge true and

accurate, but all instructions, recommendations and suggestions are made

without guarantee. Since the conditions of use are beyond their control,

Monsanto Company and its subsidiaries disclaim any liability for loss or

damage suffered from use of this information. Furthermore no liability is

accepted if use of any product in accordance with these instructions, rec-

ommendations and suggestions infringes any patent.

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ROUNDUP RTU FASTER ACTING FORMULA - 3746/E/1 - Eff 22/03/2000